The project will demonstrate a CO2-free step-change production process for silicon metal and silicon - aluminium alloys at TRL 6-8. The recently patented production process applies Al scrap and/or aluminum dross to metallothermically reduce quartz in liquid CaO-SiO2 slag, producing Si or an AlSi alloy and a CaO-Al2O3 slag, which is, in turn, hydrometallurgically treated to produce alumina (Al2O3) and calcia (CaO). The CaO is recycled into the making of the CaO-SiO2 slag which is used in the reduction process.
The main advantages of this new integrated process are the following:
- The process is CO2 free and has a lower specific energy consumption than the current SAF process. Depending on material input, different products may be produced
- The process reconstitutes waste material (currently landfilled) from the aluminum process to primary feed for the Al electrolysis process
- The process is very versatile in the use of raw materials; it can use quartz fines (currently landfilled) which is not possible in the current SAF Si production process, and the ratio of Al dross/scrap reductants can be varied and may be replaced with high purity Al to produce very high purity Si.
- With the recirculation of CaO and Al2O3 materials, the only main consumable material in the present process is quartz.
- The process does not generate NOx, dust or other harmful emissions and has a very high raw material yield.
The project will be organized in several work packages (WP) as shown below.
WP1: Raw materials
WP2: Pyrometallurgical treatment
W3: Reduction and refining
WP4: Hydrometallurgy
WP5: Electrolysis
WP6: Business concepts
WP7: Technical and environmental impact
WP8: Dissemination and clustering
WP9: Management